| 1. Identity statement | |
| Reference Type | Journal Article |
| Site | marte3.sid.inpe.br |
| Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S |
| Identifier | 6qtX3pFwXQZ3r59YCT/H3KE3 |
| Repository | sid.inpe.br/iris@1905/2005/08.04.02.40.57 (restricted access) |
| Last Update | 2014:06.24.16.29.20 (UTC) administrator |
| Metadata Repository | sid.inpe.br/iris@1905/2005/08.04.02.41 |
| Metadata Last Update | 2018:06.06.03.55.41 (UTC) administrator |
| DOI | 10.1006/jcat.2002.3634 |
| ISSN | 0021-9517 |
| Label | 10501 |
| Citation Key | SantosValeRodr:2002:InAdOx |
| Title | Catalytic decomposition of hydrazine on tungsten carbide: the influence of adsorbed oxygen  |
| Project | FAPESP (Grant N. 96/2108-6) |
| Year | 2002 |
| Secondary Date | 20021014 |
| Month | Aug. |
| Access Date | 2024, Apr. 19 |
| Type of Work | journal article |
| Secondary Type | PRE PI |
| Number of Files | 1 |
| Size | 105 KiB |
| 2. Context | |
| Author | 1 Santos, J. B. O. 2 Valença, Gustavo P. 3 Rodrigues, José Augusto Jorge |
| Group | 1 2 3 LCP-INPE-MCT-BR |
| Affiliation | 1 State University of Campinas (UNICAMP) 2 State University of Campinas (UNICAMP) 3 Instituto Nacional de Pesquisas Espaciais (INPE) |
| Author e-Mail Address | 1 2 gustavo@ feq.unicamp.br 3 jajr@lcp.inpe.br |
| e-Mail Address | marcelo.pazos@inpe.br |
| Journal | Journal of Catalysis |
| Volume | 210 |
| Number | 1 |
| Pages | 1-6 |
| History (UTC) | 2013-11-10 01:08:52 :: administrator -> jefferson :: 2002 2014-06-24 16:29:21 :: jefferson -> marcelo.pazos@sid.inpe.br :: 2002 2014-06-24 16:44:08 :: marcelo.pazos@sid.inpe.br -> administrator :: 2002 2018-06-06 03:55:41 :: administrator -> :: 2002 |
| 3. Content and structure | |
| Is the master or a copy? | is the master |
| Content Stage | completed |
| Transferable | 1 |
| Content Type | External Contribution |
| Version Type | publisher |
| Keywords | combustão catálise preparação de catalisadores decomposição da hidrazina iridio temperature-programmed reaction surface-area chemisorbed oxygen reaction pathways molybdenum iridium neopentane alkanes |
| Abstract | Passivated and nonpassivated tungsten carbide (WC)powders were prepared by a temperature-programmed reaction and used as catalysts in the hydrazine decomposition reaction. All catalysts were active at 313 K. The only products of reaction were nitrogen and ammonia, suggesting that the reaction route and the rate-determining step were not modified by adsorbed oxygen. Surface oxygen atoms reacted with hydrazine, resulting in a larger decrease in the rate of reaction for the passivated solids. Excess carbon on the surface of the carbide inhibited the decomposition of hydrazine and resulted in a Decrease of ca. 48 percent in the specific surface area of the tungsten carbide. The excess carbon may be removed in flowing hydrogen at 1000 K. When compared to commercial Ir catalyst (Shell 405), WC is less active in the hydrazine decomposition reaction. |
| Area | COMB |
| Arrangement | urlib.net > BDMCI > Fonds > Produção anterior à 2021 > LABCP > Catalytic decomposition of... |
| doc Directory Content | access |
| source Directory Content | there are no files |
| agreement Directory Content | there are no files |
| 4. Conditions of access and use | |
| Language | en |
| Target File | 1-s2.0-S0021951702936341-main.pdf |
| User Group | administrator marcelo.pazos@inpe.br |
| Reader Group | administrator marcelo.pazos@inpe.br |
| Visibility | shown |
| Archiving Policy | denypublisher denyfinaldraft24 |
| Read Permission | deny from all and allow from 150.163 |
| Update Permission | not transferred |
| 5. Allied materials | |
| Next Higher Units | 8JMKD3MGPCW/3ET38CH |
| Dissemination | WEBSCI |
| Host Collection | sid.inpe.br/banon/2001/04.03.15.36 |
| 6. Notes | |
| Empty Fields | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel format isbn lineage mark mirrorrepository nextedition notes orcid parameterlist parentrepositories previousedition previouslowerunit progress resumeid rightsholder schedulinginformation secondarykey secondarymark session shorttitle sponsor subject tertiarymark tertiarytype url |